6533b85dfe1ef96bd12bf207
RESEARCH PRODUCT
Weak non-covalent interactions control the relative molecular orientation in the crystals of N-pentafluorobenzyl aniline derivatives
Kari RissanenMarkus AlbrechtArto ValkonenMichael Müllersubject
chemistry.chemical_classificationConformational changeChemistryChemieProtonationGeneral ChemistryCrystal structureElectronCondensed Matter PhysicsCrystallographychemistry.chemical_compoundAnilineNon-covalent interactionsMoleculeGeneral Materials ScienceLayer (electronics)description
The crystal structures of N-pentafluorobenzyl aniline derivatives are controlled by versatile aromatic–aromatic interactions between the electron deficient and electron rich aromatics; the parent compound (1) possesses an L shape while protonation (2–5) induces a conformational change resulting in a planar arrangement of molecules which pack in layer type structures with different molecular orientations.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-01-01 | CrystEngComm |