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RESEARCH PRODUCT
Tetrathiafulvalene-Polychlorotriphenylmethyl Dyads: Influence of Bridge and Open-Shell Characteristics on Linear and Nonlinear Optical Properties
Joaquín CalboManuel SoutoJaume VecianaEnrique OrtíImma Raterasubject
Nonlinear opticsRadicalConjugated system010402 general chemistryPhotochemistry01 natural sciencesCatalysischemistry.chemical_compoundDonor–acceptor complexesOpen shellchemistry.chemical_classification010405 organic chemistryOrganic ChemistryNonlinear opticsGeneral ChemistryElectron acceptorAcceptor3. Good health0104 chemical sciencesCrystallographychemistryIntramolecular forceTetrathiafulvaleneIntramolecular charge transferPTM radicalsTetrathiafulvalenedescription
Three conjugated donor-π-acceptor radical systems (1 a–1 c) were prepared by bridging a tetrathiafulvalene (TTF) electron-donor unit to a polychlorotriphenylmethyl (PTM) electron-acceptor radical through vinylene units of different lengths. The dependence of the intramolecular charge transfer on the length of the conjugated bridge has been analyzed by different electrochemical and spectroscopic techniques. Linear optical properties and the second-order nonlinear optical (NLO) response of these derivatives have been computed by comparing systems 1 a–1 c with the non-radical analogues (2 a–2 c). Interestingly, an enhanced NLO response is predicted for dyads 1 a–1 c with PTM in the radical form and for compounds with longer vinylene bridges. Calculations confirm the active role the bridge plays for electronic communication between the donor TTF and the acceptor PTM units.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2017-04-11 | Chemistry - A European Journal |