6533b85efe1ef96bd12bfb48

RESEARCH PRODUCT

Absorption spectrum of the f(A1g) ← X(Eg), a(F2g) electronic transition of OsF6

Maud RotgerH. SeligVincent Boudon

subject

chemistry.chemical_compoundAbsorption spectroscopyChemistryVisible bandVibronic spectroscopyAtomic physicsOsmium hexafluorideInstrumentationSpectroscopyAtomic and Molecular Physics and OpticsMolecular electronic transitionAnalytical Chemistry

description

Abstract The absorption spectrum of the visible band of OsF 6 has been recorded using a commercial spectrophotometer. The first vibronic assignments for this band have been realized using the analogy with the d ← X transition of IrF 6 . Some vibronic parameter values are derived.

https://doi.org/10.1016/s1386-1425(97)00016-4