6533b85efe1ef96bd12bff76
RESEARCH PRODUCT
Bicyclo[2.2.2]octane-1,4-dicarboxylic acid: towards transparent metal–organic frameworks
Enrique García-españaJavier Pitarch-jarqueRafael Ballesteros-garridoPedro J. Llabres-campanerB. AbarcaRafael Ballesterossubject
chemistry.chemical_classificationMaterials scienceBicyclic molecule02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesCombinatorial chemistry0104 chemical sciencesInorganic ChemistrySolventchemistry.chemical_compoundDicarboxylic acidchemistryOrganic chemistryMoleculeMetal-organic frameworkAbsorption (chemistry)0210 nano-technologyPorous mediumOctanedescription
The preparation of transparent porous materials can offer a different access towards the study of molecules under solid confined space. Metal-organic frameworks represent a unique opportunity due to their tunable pore size, however aromatic linkers present strong absorption and reduce the transparency. Herein, we report the first example of a MOF with bicyclic organic dicarboxylic linkers and its use as a solid solvent.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2017-05-24 | Dalton Transactions |