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RESEARCH PRODUCT

High Electron Mobility and Disorder Induced by Silver Ion Migration Lead to Good Thermoelectric Performance in the Argyrodite Ag8SiSe6

Wolfgang TremelUte KolbKai S. WeldertBarbara K. HeepYaşar KrysiakWolfgang G. ZeierTristan W. DayG. Jeffrey Snyder

subject

Materials scienceGeneral Chemical EngineeringArgyroditeSilver ionNanotechnology02 engineering and technologyGeneral Chemistryengineering.material010402 general chemistry021001 nanoscience & nanotechnologyThermoelectric materials01 natural sciencesEngineering physics0104 chemical sciencesThermoelectric generatorThermalThermoelectric effectMaterials Chemistryengineering0210 nano-technologyHigh electron

description

Superionic chalcopyrites have recently attracted interest in their use as potential thermoelectric materials because of extraordinary low thermal conductivities. To overcome long-term stability issues in thermoelectric generators using superionic materials at evaluated temperatures, materials need to be found that show good thermoelectric performance at moderate temperatures. Here, we present the structural and thermoelectric properties of the argyrodite Ag8SiSe6, which exhibits promising thermoelectric performance close to room temperature.

https://doi.org/10.1021/acs.chemmater.7b00767