6533b85ffe1ef96bd12c1287

RESEARCH PRODUCT

Characterization of blends with polyamide 6 and ethylene acrylic acid copolymers at different acrylic acid content

Antonino ValenzaAnnamaria ViscoD Acierno

subject

Materials sciencePolymers and Plasticscompatibilizationpolyamide 6Hydrogen bondOrganic Chemistryethylene acrylic acid copolymerCompatibilizationBlendPolyethylenechemistry.chemical_compoundEnd-groupSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialichemistryPolymer chemistryPolyamideCopolymerblendscharacterizationPolymer blendblends; compatibilization; ethylene acrylic acid copolymer; polyamide 6; characterizationAcrylic acid

description

In this work the morphological, calorimetric, rheological and mechanical behaviour and fourier transmission infrared analysis of blends made with polyamide 6 (PA6) and ethylene acrylic acid copolymers (EAA) containing different amount of acrylic acid were investigated. The results observed from the sample characterizations evidenced as acrylic acid cause a compatibilizing effect between polyethylene and polyamide components with modifications of blends morphology and mechanical behaviour. These effects are enhanced with increase of the acrylic acid content in the copolymer and they were attributed generally to hydrogen bond interactions among the acrylic acid group and the functional groups of the polyamide. A more significant compatibilization phenomenon is obtained in blends containing higher amino terminal group concentration in the polyamide suggesting that these functional groups interact better with acrylic groups of the copolymer than the carboxylic ones.

http://hdl.handle.net/20.500.11769/241078