Intramolecular 1,5-S...N σ-hole interaction in (E)-N′-(pyridin-4-ylmethylidene)thiophene-2-carbohydrazide

6533b85ffe1ef96bd12c13d3

RESEARCH PRODUCT

Intramolecular 1,5-S...N σ-hole interaction in (E)-N′-(pyridin-4-ylmethylidene)thiophene-2-carbohydrazide

Thomas P. Mawhinney Valeri V. Mossine Steven P. Kelley

subject

crystal structure hirshfeld surface Double bond Imine Stacking Crystal structure Carbohydrazide 010402 general chemistry Ring (chemistry)01 natural sciences Research Communications energy frameworks lcsh:Chemistry chemistry.chemical_compound chalcogen bonding General Materials Science chemistry.chemical_classification Quantitative Biology::Biomolecules intermolecular interaction energies 010405 organic chemistry Hydrogen bond General Chemistry intermolecular interaction energies hydrogen bonding Condensed Matter Physics 4-pyridinecarboxaldehyde 2-thienyl hydrazone 0104 chemical sciences Crystallography lcsh:QD1-999 chemistry 4-pyridinecarboxaldehyde 2-thienyl hydrazone Monoclinic crystal system

description

The hydrazide-hydrazone forms inverse dimers via hydrogen bonding, but its conformation is defined by the presence of an intramolecular chalcogen bond. Electrostatic forces dominate in the crystal packing and give rise to a layered supramolecular structure.

year	journal	country	edition	language
2020-04-01	Acta Crystallographica Section E Crystallographic Communications

https://doi.org/10.1107/s2056989020003011

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