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RESEARCH PRODUCT

Liquid crystal polymers from swallow-tailed mesogens

Joachim H. WendorffMartina EbertIvan CabreraHelmut Ringsdorf

subject

chemistry.chemical_classificationMaterials sciencechemistry.chemical_elementGeneral ChemistryPolymerCondensed Matter PhysicsRing (chemistry)chemistry.chemical_compoundMonomerchemistryLiquid crystalPhase (matter)Organic chemistryGeneral Materials SciencePlatinum

description

Abstract Swallow-tailed compounds containing an acetylenic unit have been synthesized. Only those compounds with a three ring structure exhibited liquid-crystalline phases. The platinum catalysed addition of these monomers to compounds containing Si-H groups was used to synthesize polymeric materials. Only those polymers with the tetramethyldisiloxane unit showed mesophases. The synthesis, characterization, and phase behaviour are described.

https://doi.org/10.1080/02678299008047338