ChemInform Abstract: A Liquid-Liquid Biphasic Homogeneous Organocatalytic Aldol Protocol Based on the Use of a Silica Gel Bound Multilayered Ionic Liquid Phase.

6533b85ffe1ef96bd12c1a70

RESEARCH PRODUCT

ChemInform Abstract: A Liquid-Liquid Biphasic Homogeneous Organocatalytic Aldol Protocol Based on the Use of a Silica Gel Bound Multilayered Ionic Liquid Phase.

Arianna Quintavalla Francesco Giacalone Marco Lombardo Claudio Trombini Michelangelo Gruttadauria Elisa Montroni

subject

chemistry.chemical_classification chemistry.chemical_compound chemistry Chemical engineering Aldol reaction Covalent bond Silica gel Organocatalysis Phase (matter)Ionic liquid Cyclohexanone General Medicine Aldehyde

description

Key feature of the title protocol is the use of a cis-ion-tagged proline dissolved in a liquid film on a multilayered ionic liquid covalently bound to silica. The resulting catalytically active material is soaked in cyclohexanone and water to form a semi-transparent gel which then reacts with the aldehyde.

year	journal	country	edition	language
2012-10-11	ChemInform

https://doi.org/10.1002/chin.201245076

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