(Cycloheptadienyl)diphenylphosphine: A Versatile Hybrid Ligand

6533b85ffe1ef96bd12c248b

RESEARCH PRODUCT

(Cycloheptadienyl)diphenylphosphine: A Versatile Hybrid Ligand

Michel Picquet Vincent Rampazzi Arnaud Perrier Jean-cyrille Hierso Pierre Le Gendre Ewen Bodio Philippe Richard Alexandre Massard

subject

Inorganic Chemistry chemistry.chemical_compound Olefin fiber Denticity Diphenylphosphine chemistry Diene Ligand Organic Chemistry Physical and Theoretical Chemistry Medicinal chemistry

description

(3,5-Cycloheptadienyl)diphenylphosphine is easily synthesized from the reaction of diphenylphosphine with 1,3,5-cycloheptatriene. This new phosphine-diene has been coordinated as a monodentate P ligand with Pt, Pd, Au, Ni, and Ru; as a bidentate (P, olefin) ligand with Pt and Pd; and as a tridentate (P, diene) ligand with Rh. Fluxional properties of several complexes have been studied via NMR experiments and theoretical consideration.

year	journal	country	edition	language
2012-01-20	Organometallics

https://doi.org/10.1021/om200999n

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