6533b85ffe1ef96bd12c2724

RESEARCH PRODUCT

Kinetics of Zn2+ complexation by a ditopic phenanthroline-azamacrocyclic scorpiand-like receptor.

Enrique García-españaRaquel GavaraSalvador BlascoOscar GadeaFernando PinaJorge González

subject

Aza CompoundsStereochemistryPhenanthrolineKineticsMetals and AlloysGeneral ChemistryHydrogen-Ion ConcentrationCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsMetalchemistry.chemical_compoundKineticsZincchemistryCoordination Complexesvisual_artPolymer chemistryMaterials ChemistryCeramics and Compositesvisual_art.visual_art_mediumSlow MovementPolyamineReceptorPhenanthrolines

description

Coordination of Zn(2+) to a ditopic phenanthroline-macrocycle receptor takes place in three steps, the first one being the coordination to the phenanthroline, followed by the slow movement of the metal to the polyamine macrocycle and a final re-arrangement to coordinate the pendent arm.

10.1039/c2cc16831fhttps://pubmed.ncbi.nlm.nih.gov/22234289