6533b85ffe1ef96bd12c27ad

RESEARCH PRODUCT

Micro-determination of dithiocarbamates in pesticide formulations using voltammetry

Diana AmorelloSantino Orecchio

subject

voltammetryZiramChromatographyThiramManebformulationPesticideSettore CHIM/12 - Chimica Dell'Ambiente E Dei Beni CulturaliAnalytical Chemistrydithiocarbamatechemistry.chemical_compoundchemistryZinebAdsorptive stripping voltammetrySettore CHIM/01 - Chimica AnaliticaMancozebVoltammetryMicro determinationpesticideSpectroscopy

description

Abstract The purpose of this work was to develop a reliable method for the micro-determination of dithiocarbamates (mancozeb, maneb, propineb, nabam, Na(CH3)2DTC, zineb, ziram, ferbam and thiram) in pesticide formulations for agriculture using adsorptive stripping voltammetry (AdSV). The accuracy of analytical method was valued by analyzing simulate formulation samples prepared by us with known amounts of active ingredients. In addition, the applicability of the AdSV procedure for the analysis of DTCs and EBDTCs in micro-samples was evaluated by estimating its recoveries from spiked commercial formulate samples. The accuracy, valuated as recovery percentage ranged between 85% and 97%. The precision ranged from 1.3 to 6.1%.

yearjournalcountryeditionlanguage
2013-09-01Microchemical Journal
https://doi.org/10.1016/j.microc.2013.05.002