Palladium-Catalysed Amination of 1,8- and 1,5-Dichloroanthracenes and 1,8- and 1,5-Dichloroanthraquinones

6533b85ffe1ef96bd12c2810

RESEARCH PRODUCT

Palladium-Catalysed Amination of 1,8- and 1,5-Dichloroanthracenes and 1,8- and 1,5-Dichloroanthraquinones

Roger Guilard Irina P. Beletskaya Alexei D. Averin Alexei D. Averin Franck Denat Alla G. Bessmertnykh Alla G. Bessmertnykh

subject

Anthracene 010405 organic chemistry Organic Chemistry chemistry.chemical_element Homogeneous catalysis General Medicine Electrophilic aromatic substitution 010402 general chemistry 01 natural sciences Anthraquinone Nitrogen Catalysis 0104 chemical sciences chemistry.chemical_compound chemistry Polymer chemistry Cyclam Organic chemistry [CHIM]Chemical Sciences Physical and Theoretical Chemistry ComputingMilieux_MISCELLANEOUS Amination Palladium

description

Diamino derivatives of anthracene and anthraquinone have been synthesised by palladium-catalysed coupling of 1,8-dichloroanthracene and 1,8-dichloroanthraquinone with a wide range of aliphatic and aromatic primary and secondary amines. The use of polyamines gave rise to a large number of new nitrogen- and oxygen-containing macrocycles incorporating anthracene or anthraquinone moieties. The method has also been employed for the preparation of bismacrocycles in which two cyclam or azacrown units are linked together by an anthracene bridge through C(sp2)−N bonds. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

year	journal	country	edition	language
2005-06-07	European Journal of Organic Chemistry

https://doi.org/10.1002/ejoc.200400455

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