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RESEARCH PRODUCT
ChemInform Abstract: Electroorganic Synthesis of Nitriles via a Halogen-Free Domino Oxidation-Reduction Sequence.
Marius Franziskus HartmerSiegfried R. Waldvogelsubject
chemistry.chemical_compoundNitrilechemistryElectrodeMoietyHalogen freeSequence (biology)Oxidation reductionGeneral MedicineGraphiteCombinatorial chemistryDominodescription
A direct electroorganic sequence yielding nitriles from oximes in undivided cells is reported. Despite the fact that intermediate nitrile oxides might be formed, the method is viable to prepare benzonitriles without substituents ortho to the aldoxime moiety. This constant current method is easy to perform for a broad scope of substrates and employs common electrodes, such as graphite and lead.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2016-02-01 | ChemInform |