6533b860fe1ef96bd12c30f8
RESEARCH PRODUCT
Rare isotopic species of hydrogen sulfide: the rotational spectrum of H236S
Gabriele CazzoliJürgen GaussCristina Puzzarinisubject
Physicsmolecular dataHydrogen sulfideAnalytical chemistrymethods: laboratory: molecularAstronomy and AstrophysicsISM: moleculeAstrophysicschemistry.chemical_compoundchemistrySpace and Planetary ScienceRotational spectrumsubmillimeter: ISMIsotopologuemethods: data analysitechniques: spectroscopicdescription
The rotational spectrum of the 36 S-bearing isotopologue of hydrogen sulfide (H2S) has been investigated for the first time in the 167 GHz−1.6 THz frequency range, thus providing an accurate and reliable set of spectroscopic parameters. The experimental investigation was backed up by state-of-the-art quantum-chemical calculations, which also allowed us to demonstrate the incorrectness of the previously reported spectroscopic constants. The present results are of suitable accuracy to attempt the astrophysical detection of the isotopic species under consideration. Finally, reliable predictions for the spectroscopic constants of other rare isotopologues of H2S, namely the mono- and bi-deuterated species containing 33 Sa nd 34 S, are provided.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2014-06-01 | Astronomy & Astrophysics |