6533b862fe1ef96bd12c60a3

RESEARCH PRODUCT

The EFG in oxonium ferric orthophosphate hydrate and related compounds

W. Meisel

subject

Nuclear and High Energy PhysicsChemistryQuadrupoleInorganic chemistrymedicineFerricPhysical and Theoretical ChemistryCondensed Matter PhysicsHydrateOxonium ionAtomic and Molecular Physics and Opticsmedicine.drug

description

The point cherge model was used to interpret the small quadrupole spilting of Fe3H15(PO4)8·5H2O by comparing it with related phosphates of known structure. The approximation is sufficient as long as octahedrally coordinated compounds are compared for which Vzz and η do not change their signs.

https://doi.org/10.1007/bf02049105