6533b862fe1ef96bd12c6134
RESEARCH PRODUCT
ChemInform Abstract: Reactions of 3-Vinylindole Derivatives with Dienophiles.
Ulf PindurMercedes Medio-simónsubject
Reaction conditionsAddition reactionchemistry.chemical_compoundChemistryCarbazoleYield (chemistry)Organic chemistryGeneral MedicineEne reactionAdductdescription
Reactions of 3-(1-cyclohexenyl)-1,2-dimethylindole (1a) and the 1,2-dihydrocarbazole 1b with some carbo- and heterodienophiles are described. Thus, compound 1a reacts to give ene, Michael-type, and Diels-Alder adducts, depending on the dienophile and reaction conditions. The 3-vinylindole 1b reacts with 4-phenyl-1,2,4-triazoline-3,5-dione or N-phenylmaleimide in a dehydrogenative reaction to yield the fully aromatized carbazole 8.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-08-22 | ChemInform |