6533b862fe1ef96bd12c6b42

RESEARCH PRODUCT

The influence of phosphoric acid on steel and on its corrosion products: a Mössbauer spectroscopic approach

H.-j. GuttmannW. MeiselPhilipp Gütlich

subject

ChemistryGeneral Chemical EngineeringInorganic chemistryGeneral ChemistryHematitePhosphateCorrosionMetalchemistry.chemical_compoundvisual_artMössbauer spectroscopyvisual_art.visual_art_mediummedicineFerricGeneral Materials ScienceAcid treatmentPhosphoric acidNuclear chemistrymedicine.drug

description

Mossbauer spectroscopy was used to study corroded iron after treatment with phosphoric acid or commercial rust transformers. It was found that treatment produced normal iron phosphates from metallic iron, hematite and FeO, and acid ferric phosphate FeH 3 (POI4I)I2I. 2.5H 2 O from alphaand gamma Fe 2 O 3 and alpha, beta, and gammaFeOOH. When these last are present, phosph oric acid treatment does not produce a protective, inhibiting layer. See also AATA 19-702. -- AATA

https://doi.org/10.1016/0010-938x(83)90085-9