6533b862fe1ef96bd12c6bed

RESEARCH PRODUCT

Cross-linked PEEK-WC proton exchange membrane for fuel cell

Mkhulu MatheGuntars VaivarsHongze Luo

subject

Renewable Energy Sustainability and the EnvironmentEnergy Engineering and Power TechnologyProton exchange membrane fuel cellConductivityCondensed Matter Physicschemistry.chemical_compoundFuel TechnologyMembranechemistryPermeability (electromagnetism)NafionHydrogen fuelPeekMethanolNuclear chemistry

description

Abstract The low cost proton exchange membrane was prepared by cross-linking water soluble sulfonated-sulfinated poly(oxa- p -phenylene-3,3-phthalido- p -phenylene-oxa- p -phenylene-oxy-phenylene) (SsPEEK-WC). The prepared cross-linked membrane became insoluble in water, and exhibited high proton conductivity, 2.9 × 10 −2  S/cm at room temperature. The proton conductivity was comparable with that of Nafion ® 117 membrane (6.2 × 10 −2  S/cm). The methanol permeability of the cross-linked membrane was 1.6 × 10 −7  cm 2 /s, much lower than that of Nafion ® 117 membrane.

https://doi.org/10.1016/j.ijhydene.2009.08.024