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RESEARCH PRODUCT
Assessing the Electrochemical Performance of Different Nanostructured CeO2 Samples as Anodes for Lithium-Ion Batteries
Farah LamaraNedjemeddine BounarBenjamín SolsonaFrancisco J. LlopisMaría Pilar PicoDaniel Alonso-domínguezMaría Luisa LópezInmaculada ÁLvarez-serranosubject
Fluid Flow and Transfer ProcessesTechnologyQH301-705.5Process Chemistry and TechnologyTPhysicsQC1-999lithium-ion batteriesGeneral EngineeringEngineering (General). Civil engineering (General)Química inorgánicaComputer Science Applicationsanode materialsChemistryanode materials; cerium oxide; lithium-ion batteries; nanostructured ceriananostructured ceriaGeneral Materials ScienceTA1-2040Biology (General)Instrumentationcerium oxideQD1-999description
In this work, six samples of CeO2 are successfully prepared by diverse synthesis routes leading to different microstructures regarding both morphology and particle size. The structural and microstructural characteristics presented by the samples and their influence on the electrochemical response of the prepared anodes are analyzed. In particular, the Ce-CMK3 sample, synthesized from a mesoporous carbon obtained through a CMK3 silica template, displays an enhanced electrochemical response. Thus, capacity values of ~220 mA h g−1 are obtained at a current rate of 0.155 A g−1 after 50 cycles and an excellent cyclability at intermediate current densities. On the other hand, it is observed that the capacity values are satisfactorily recovered at 0.31 A g−1, displaying ~100 mA h g−1 after 550 cycles and efficiencies close to 100%. The electrochemical performance is interpreted considering the microstructural peculiarities of this anode, which are deeply analyzed.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2021-12-21 | Applied Sciences; Volume 12; Issue 1; Pages: 22 |