6533b86cfe1ef96bd12c7f62

RESEARCH PRODUCT

A dinuclear rhodium(III) complex with the N,N′-ethylenebis(salicylideneiminato) (salen) ligand in a bridging bis-bidentate mode of coordination. Crystal structure of [{Rh(η2-(C6H4)PPh2)(η2-P(o-ClC6H4)Ph2)}2(salen)](SbF6)2

Pascual LahuertaSantiago García-grandaF. Gómez-beltránRamón Martínez-máñezJulio Latorre

subject

DenticitySchiff baseStereochemistrychemistry.chemical_elementCrystal structureRhodiumInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryMetal salen complexesSalen ligandX-ray crystallographyMaterials ChemistryMoleculePhysical and Theoretical Chemistry

description

In this communication we describe the synthesis and crystal structure of the complex [{Rh(η 2 -(C 6 H 4 )PPh 2 )(η 2 -P(o-ClC 6 H 4 )Ph 2 )} 2 (salen)]-(SbF 6 ) 2 , showing the bridging configuration of the salen ligand

https://doi.org/10.1016/s0020-1693(00)80932-9