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RESEARCH PRODUCT
Synthesis and Reactivity of 2-Aminophenylpalladium(II) Complexes: Insertion Reactions of Oxygen and Carbon Monoxide into Carbon−Palladium Bonds—New Examples of “Transphobia”
M. Carmen Ramírez De ArellanoJosé-antonio AbadAndrew D. FranklandJosé Vicentesubject
chemistry.chemical_compoundChemistryOrganic ChemistryPolymer chemistrychemistry.chemical_elementGeneral ChemistryPhotochemistryOxygenCatalysisPalladiumCarbon monoxidedescription
Insertion of CO into 2-aminophenylpalladium complexes leads to 2-aminobenzoylpalladium derivatives. When these compounds are forced to coordinate a carbon donor and a phosphane ligand in the trans position, a C−P coupling process or an insertion of oxygen occurs (see scheme). In this case, a dinuclear palladium complex containing a bridging anthranilato ligand is isolated.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1999-10-01 | Chemistry - A European Journal |