6533b86cfe1ef96bd12c7f98
RESEARCH PRODUCT
Monolayers of dipalmitoylphosphatidylcholine at the oil-water interface
Martin ThomaHelmuth Möhwaldsubject
Alkanechemistry.chemical_classificationChromatographyDodecaneAnalytical chemistryHexadecanechemistry.chemical_compoundColloid and Surface ChemistryHydrocarbonchemistryDipalmitoylphosphatidylcholinePhase (matter)PhosphatidylcholineMonolayerdescription
Abstract Monolayers of dipalmitoylphosphatidylcholine at the interfaces waterbicylohexyl, waterdodecane and waterhexadecane were studied by fluorescence microscopy and thermodynamic measurements. The experiments show that the oil also partitions in the liquid condensed (LC) monolayer phase with concentration depending on the type of oil and the lateral pressure. In contrast to monolayers of dipalmitoylphosphatidylethanolamine the larger molecular area per head group enables oil partitioning in the LC phase even if there is a mismatch between the aliphatic tails of liquid and alkane.
year | journal | country | edition | language |
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1995-02-01 | Colloids and Surfaces A: Physicochemical and Engineering Aspects |