Search results for "Hexadecane"

showing 10 items of 17 documents

Monolayers of dipalmitoylphosphatidylcholine at the oil-water interface

1995

Abstract Monolayers of dipalmitoylphosphatidylcholine at the interfaces waterbicylohexyl, waterdodecane and waterhexadecane were studied by fluorescence microscopy and thermodynamic measurements. The experiments show that the oil also partitions in the liquid condensed (LC) monolayer phase with concentration depending on the type of oil and the lateral pressure. In contrast to monolayers of dipalmitoylphosphatidylethanolamine the larger molecular area per head group enables oil partitioning in the LC phase even if there is a mismatch between the aliphatic tails of liquid and alkane.

Alkanechemistry.chemical_classificationChromatographyDodecaneAnalytical chemistryHexadecanechemistry.chemical_compoundColloid and Surface ChemistryHydrocarbonchemistryDipalmitoylphosphatidylcholinePhase (matter)PhosphatidylcholineMonolayerColloids and Surfaces A: Physicochemical and Engineering Aspects
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1987

The intrinsic viscosities, [η], for the ternary systems alkane (1)/2-butanone (2)/poly(dimethylsiloxane) (PDMS)(3), with the alkanes decane, dodecane and hexadecane, are determined at 20,0°C. The constants a of the Mark-Houwink equation and the constant of the unperturbed dimensions, KΘ, of the polymer are evaluated over the whole composition range of the binary solvent mixture. [η] shows a pronounced maximum at intermediate compositions as found in cosolvent mixtures. In these cosolvent mixtures, the numerical values of KΘ are higher than in the single-component solvents, because the cosolvent mixtures correspond to a mixed solvent with an excess free energy, GE ≥ 0, the increase in KΘ bei…

Alkanechemistry.chemical_classificationchemistry.chemical_compoundViscositychemistryVirial coefficientDodecaneIntrinsic viscosityPolymer chemistryDecaneHexadecaneTernary operationDie Makromolekulare Chemie
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Probing the spectral dynamics of single terrylenediimide molecules in low-temperature solids

1999

Abstract Fluorescence excitation lines of single terrylenediimide (TDI) molecules were recorded in the matrices polyethylene (PE) and hexadecane (HD) in the temperature range between 1.4 and 13 K. From line width distributions at 2.5 K in both matrices it was concluded that the disorder, theoretically modeled by a distribution of two-level systems (TLSs), is about three times stronger in PE. Temperature-dependent measurements of the line shape of single chromophores showed a reversible broadening and shift of the zero-phonon lines. We attributed this behavior to dephasing caused by pseudolocal phonons and to spectral diffusion caused by fluctuating TLSs of the disordered host. Following the…

ChemistryPhononDephasingAnalytical chemistryGeneral Physics and AstronomyChromophoreHexadecaneAtmospheric temperature rangeMolecular physicschemistry.chemical_compoundPhysical and Theoretical ChemistryDiffusion (business)ExcitationLine (formation)Chemical Physics
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Proteomics highlights metabolic changes associated with n-hexadecane utilization in a Streptomyces coelicolor engineered strain.

2011

Proteomics n-hexadecane utilization Streptomyces coelicolor genetically engineered strain.
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Differential proteomic analysis of an engineered Streptomyces coelicolor strain reveals metabolic pathways supporting growth on n-hexadecane

2012

The alkB gene, encoding an alkane monooxygenase in the actinomycete Gordonia sp. SoCg, was expressed in the non-alkane-degrading actinomycete Streptomyces coelicolor M145. The resulting engineered strain, M145-AH, can grow on n-hexadecane as sole carbon source. To unravel proteins associated with growth on n-alkanes, proteome of M145-AH after 6, 24, and 48 h of incubation in the Bushnell-Haas (BH) mineral medium containing n-hexadecane as sole carbon source (H condition) and in BH without any carbon source (0 condition) were compared using 2D-differential gel electrophoresis. Proteome analysis revealed significant changes only at 48 h, showing 48 differentially abundant proteins identified …

ProteomicsProteomeAlkBProtein metabolismGene ExpressionStreptomyces coelicolorSettore BIO/19 - Microbiologia GeneraleProteomicsApplied Microbiology and BiotechnologyStreptomyceschemistry.chemical_compoundAlkanesElectrophoresis Gel Two-DimensionalbiologyStreptomyces coelicolorProteomicGeneral MedicineMetabolism2d-dige analysisMembrane transportbiology.organism_classificationCarbonRecombinant ProteinsStreptomycesCulture MediaN-alkane monoxygenaseStreptomyceN-hexadecane utilizationchemistryBiochemistryEngineered strainProteomebiology.protein2D-DIGE analysiCytochrome P-450 CYP4AMetabolic Networks and PathwaysBiotechnologyApplied Microbiology and Biotechnology
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CCDC 781080: Experimental Crystal Structure Determination

2011

Related Article: J.-P.Collin, S.Durot, M.Keller, J.-S.Sauvage, Y.Trolez, M.Cetina, K.Rissanen|2011|Chem.-Eur.J.|17|947|doi:10.1002/chem.201002220

Space GroupCrystallography(3)-((mu2-38-bis(5-(2-(Trimethylsilyl)ethynyl)-2-pyridyl)-47-phenanthroline)-bis(29-(116-bis(41-phenylene)-147101316-hexaoxahexadecane)-110-phenanthroline)-di-zinc(ii)) pseudorotaxane tetrakis(trifluoromethanesulfonate) acetone solvate monohydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1439082: Experimental Crystal Structure Determination

2016

Related Article: Nicolas Sok, Isabelle Baglin, Yoann Rousselin, Frederic Boschetti, Claire Bernhard, Christine Goze, Franck Denat|2016|New J.Chem.|40|5829|doi:10.1039/C5NJ03488D

Space GroupCrystallography(411-dibenzyl-14811-tetraazabicyclo[6.6.2]hexadecane-1516-dicarbonitrile)-nitrato-copper(ii) nitrate methanol solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1439080: Experimental Crystal Structure Determination

2016

Related Article: Nicolas Sok, Isabelle Baglin, Yoann Rousselin, Frederic Boschetti, Claire Bernhard, Christine Goze, Franck Denat|2016|New J.Chem.|40|5829|doi:10.1039/C5NJ03488D

Space GroupCrystallographyCrystal SystemCrystal Structure411-dibenzyl-14811-tetraazabicyclo[6.6.2]hexadecane-1516-dicarbonitrileCell ParametersExperimental 3D Coordinates
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CCDC 1439081: Experimental Crystal Structure Determination

2016

Related Article: Nicolas Sok, Isabelle Baglin, Yoann Rousselin, Frederic Boschetti, Claire Bernhard, Christine Goze, Franck Denat|2016|New J.Chem.|40|5829|doi:10.1039/C5NJ03488D

Space GroupCrystallographyCrystal SystemCrystal Structure411-dibenzyl-14811-tetraazabicyclo[6.6.2]hexadecane-1516-dicarbonitrileCell ParametersExperimental 3D Coordinates
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CCDC 750763: Experimental Crystal Structure Determination

2009

Related Article: Y.Rousselin, F.Denat, B.Lebeau, A.Walcarius|2009|Acta Crystallogr.,Sect.E:Struct.Rep.Online|65|o2531|doi:10.1107/S1600536809038112

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters18-bis[3-(triethoxysilyl)propyl]-411-diaza-18-diazoniatricyclo[9.3.1.1^48^]hexadecane diiodideExperimental 3D Coordinates
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