6533b86dfe1ef96bd12c9387

RESEARCH PRODUCT

III. Darstellung und molekülstruktur von triazoboracyclooctanen

U.w. GerwarthK.-d. Müller

subject

Inorganic Chemistrychemistry.chemical_compoundchemistryInsertion reactionComputational chemistryOrganic ChemistryMaterials ChemistryPhysical and Theoretical ChemistryRing (chemistry)BiochemistryPhenylisocyanate

description

Abstract The aminoboration of phenylisocyanate or phenylisothiocyanate with 2-phenyl-1,3,2-diazabora-cyclohexane yields under ring expansion the eight-membered BNC-heterocycles 2,3-diphenyl-1,3,5-triaza-2-bora-cyclooctane-4-one or 2,3-diphenyl-1,3,5-triaza-2-bora-cyclooctane-4-thione, respectively. Isomeric structures, which can appear in the insertion reaction, are discussed on the basis of spectroscopic data.

yearjournalcountryeditionlanguage
1976-04-01Journal of Organometallic Chemistry
https://doi.org/10.1016/s0022-328x(00)90154-2