6533b86dfe1ef96bd12c9404

RESEARCH PRODUCT

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Volker BöhmerJagannath NathWerner KernMedini K. Pal

subject

Circular dichroismchemistry.chemical_compoundAqueous solutionchemistryDiaminePolymer chemistryPolyglutamic acidRandom coil

description

The interaction of poly(L-glutamic acid) with 3,6-dioxaoctamethylenediamine was studied by circular dichroism spectroscopy under different conditions. In aqueous solution at pH 5,6 and in aqueous 1,4-dioxane (30–50 vol.-%) at pH 7,3 the conformation of poly(L-glutamic acid) was completely changed from α-helical to random coil in the presence of an excess of the diamine.

https://doi.org/10.1002/macp.1981.021820605