6533b86dfe1ef96bd12c94bb

RESEARCH PRODUCT

Thermo- and light responsive micellation of azobenzene containing block copolymers

Patrick TheatoPatrick TheatoFlorian D. Jochum

subject

chemistry.chemical_classificationMaterials scienceeducationtechnology industry and agricultureMetals and Alloysmacromolecular substancesGeneral ChemistryPolymerFluorescenceCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundLight responsivechemistryAzobenzeneChemical engineeringPolymer chemistryMaterials ChemistryCeramics and CompositesLight inducedCopolymerTurbidimetry

description

In this communication, the synthesis and characterization of thermo- and light responsive block copolymers is reported. PEO-b-PNIPAM polymers with azobenzene moieties were prepared and analyzed by turbidimetry, fluorescence, NMR and DLS measurements. A temperature controlled reversible formation as well as a light induced disruption and reformation of micellar structures in water was found.

https://doi.org/10.1039/c0cc01288b