6533b86dfe1ef96bd12c9d6f

RESEARCH PRODUCT

Rare earth doped glass–ceramics containing NaLaF4 nanocrystals

Guna KriekeE. ElstsKrisjanis SmitsJ. JansonsAleksejs ZolotarjovsUldis RogulisK. KundzinsAnatolijs Sarakovskis

subject

Materials scienceScanning electron microscopePraseodymiumAnalytical chemistrychemistry.chemical_elementMineralogyCathodoluminescenceTerbium02 engineering and technology01 natural sciencesNeodymiumInorganic ChemistryDifferential thermal analysis0103 physical sciencesElectrical and Electronic EngineeringPhysical and Theoretical ChemistrySpectroscopy010302 applied physicsOrganic Chemistry021001 nanoscience & nanotechnologyAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic MaterialschemistryDysprosium0210 nano-technologyLuminescence

description

Abstract Oxyfluoride glasses 16Na 2 O–9NaF–5LaF 3 –7Al 2 O 3 –63SiO 2 (mol%) activated with 3% terbium, dysprosium, praseodymium and neodymium fluorides have been prepared and studied by differential thermal analysis, cathodoluminescence, X-ray induced luminescence, X-ray diffraction, scanning electron microscopy and energy dispersive X-ray spectroscopy. We found out that the presence of crystalline phase enhances the X-ray induced luminescence intensity. X-ray induced luminescence is the most intense for the sample activated with terbium and treated at 700 °C, whereas the praseodymium and neodymium activated samples have the fastest decay times.

https://doi.org/10.1016/j.optmat.2016.01.005