6533b86dfe1ef96bd12c9ef0

RESEARCH PRODUCT

Studies on mechanism and physico-chemical parameters at the origin of the cement setting II. Physico-chemical parameters determining the coagulation process

S.p. JiangAndré NonatJean-claude Mutin

subject

CementMaterials scienceMetal ions in aqueous solutionIonic bondingMineralogychemistry.chemical_elementBuilding and ConstructionCalciumChemical engineeringchemistryParticle-size distributionParticleCoagulation (water treatment)DLVO theoryGeneral Materials Science

description

The physico-chemical parameters determining the coagulation of cements grains previously identified as the first fundamental process of cement setting have been investigated in diluted suspensions using an adapted granulometric method. The analysis of the influence of the ionic concentration in solution on the coagulation reveals that calcium concentration is the parameter which determines the particle interactions. There exists a minimum critical concentration of calcium ions in solution which is required to occur the coagulation of cement particles and a dispersive effect appears for very high concentrations. The results are discussed in relation with DLVO theory and specific interactions.

https://doi.org/10.1016/s0008-8846(96)85036-8