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RESEARCH PRODUCT
Single-Crystal X-Ray Diffraction Study of Pressure and Temperature-Induced Spin Trapping in a Bistable Iron(II) Hofmann Framework.
Simon ParsonsGemma F. TurnerAndrés E. GoetaM. Carmen MuñozJosé Antonio RealFallyn CampbellStephen A. Moggachsubject
DiffractionMaterials scienceBistabilitySpin trapping010405 organic chemistryGeneral MedicineGeneral Chemistry010402 general chemistry01 natural sciencesTemperature inducedMolecular physicsCatalysis0104 chemical sciencesSpin crossoverThermalX-ray crystallographyCondensed Matter::Strongly Correlated ElectronsSingle crystaldescription
High-pressure single-crystal X-ray diffraction has been used to trap both the low-spin (LS) and high-spin (HS) states of the iron(II) Hofmann spin crossover framework, [FeII (pdm)(H2 O)[Ag(CN)2 ]2 ⋅H2 O, under identical experimental conditions, allowing the structural changes arising from the spin-transition to be deconvoluted from previously reported thermal effects.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2020-02-17 | Angewandte Chemie (International ed. in English) |