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RESEARCH PRODUCT
Methylresorcinarene: a reaction vessel to control the coordination geometry of copper(II) in pyridine N-oxide copper(II) complexes
Rakesh PuttreddyNgong Kodiah Beyehsubject
Magnetic Resonance SpectroscopyPyridinesmethylresorcinareneInorganic chemistrychemistry.chemical_elementPyridine-N-oxideNuclear magnetic resonance spectroscopyCopperInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryOctahedronX-Ray DiffractionCoordination ComplexesPyridinecopper complexesCalixarenesProtecting groupSingle crystalta116CopperCoordination geometrydescription
Pyridine and 2-picolinic acid N-oxides form 2 : 2 and 2 : 1 ligand : metal (L : M) discrete L2M2 and polymeric complexes with CuCl2 and Cu(NO3)2, respectively, with copper(ii) salts. The N-oxides also form 1 : 1 host-guest complexes with methylresorcinarene. In combination, the three components form a unique 2 : 2 : 1 host-ligand-metal complex. The methylresorcinarene acts as a reaction vessel/protecting group to control the coordination of copper(ii) from cis-see-saw to trans-square planar, and from octahedral to square planar coordination geometry. These processes were studied in solution and in the solid state via(1)H NMR spectroscopy and single crystal X-ray diffraction.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2015-05-06 | Dalton Transactions |