6533b86efe1ef96bd12cc76d
RESEARCH PRODUCT
Crystallization Behaviour at High Cooling Rates of Two Polypropylenes
Stefano PiccaroloGiuseppe TitomanlioValerio BrucatoS. Alessisubject
chemistry.chemical_classificationMaterials scienceKineticsThermodynamicsCooling ratesPolymerSpectral linelaw.inventionchemistrylawPhase (matter)TacticityMolar mass distributionCrystallizationdescription
Phase distribution of quenched samples of two isotactic polypropylenes, having different molecular weight distributions, was evaluated by a deconvolution procedure of WAXD spectra. The dependence on cooling rate of the two resins shows the low molecular weights rich polymer is characterized by a faster kinetics with an α-monoclinic to mesomorphic transition taking place at higher cooling rates.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1993-01-01 |