6533b86efe1ef96bd12ccb2c
RESEARCH PRODUCT
Suzuki polycondensation with a hairpin monomer.
Karl FischerManfred SchmidtYogesh SangvikarJunji SakamotoA. Dieter Schlütersubject
Condensation polymerMolar massOrganic ChemistryMs analysisFraction (chemistry)BiochemistryGel permeation chromatographychemistry.chemical_compoundMonomerPolymerizationchemistryDynamic light scatteringPolymer chemistryPhysical and Theoretical Chemistrydescription
Two straight monomers were subjected to an AA/BB-type Suzuki polycondensation with a hairpin-shaped 1,8-anthrylene monomer as the counterpart leading to a novel polyarylene which should have the preferred conformation of a folded chain. The molar masses were determined by gel permeation chromatography and dynamic light scattering and found to be M(w) = 14,000 and M(n) = 7,000. MALDI-TOF MS analysis of a fraction provides a fingerprint of the step-growth nature of this polymerization.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2009-08-13 | Organic letters |