6533b86ffe1ef96bd12cd1bc

RESEARCH PRODUCT

A New Layered Compound Containing [PMo12O40]3- and Both 5- and 6-Coordinated Homoleptic (1-(2-Chloroethyl)tetrazole)Copper(II) Cations

Jaap G. HaasnootArno F. StassenCarlos Giménez-saizEugenia Martínez FerreroEugenio CoronadoJan Reedijk

subject

chemistry.chemical_classificationchemistry.chemical_compoundChemistryLigandPolymer chemistryPolyoxometalateInorganic chemistrychemistry.chemical_elementTetrazoleCrystal structureHomolepticCopperCoordination complex

description

The synthesis, crystal structure and physical properties of the complex obtained from the reaction between the polyoxometalate anion [PMo12O40]3- copper(II) and the ligand 1-(2-chloroethyl)tetrazole (teec) are described. This compound has been synthesized as a model for designing materials containing both magnetic polyoxometalate anions and iron(II) spin-crossover cations. Keywords. Coordination chemistry; Heterocycles; Polyoxometalates; Structure elucidation; Tetrazole.

yearjournalcountryeditionlanguage
2002-01-01
https://doi.org/10.1007/978-3-7091-6018-3_9