6533b86ffe1ef96bd12cd2ee

RESEARCH PRODUCT

Poly-iodinated closo 1,2-C 2 B 10 and nido [7,8-C 2 B 9 ] − carborane frameworks: Synthesis and consequences

Francesc TeixidorMarius LupuClara ViñasAdnana ZauletReijo Sillanpää

subject

carboranesSolvent freeStereochemistryChemistryOrganic ChemistryHalogenationsolvent freeBiochemistryInorganic ChemistryiodinationMaterials ChemistryProton NMRCarboranePhysical and Theoretical Chemistryta116acidity

description

Abstract The preparation of Cc-monosubstituted closo and nido carborane derivatives, mono-, di and tetraiodinated is reported. Some of these mono-to poly-iodinated nido carboranes are studied in terms of the acidity of the open face bridging proton, their chemical shift position in the 1H NMR, and the lesser tendency to η5-coordination in parallel to a larger number of iodo groups.

yearjournalcountryeditionlanguage
2015-12-01Journal of Organometallic Chemistry
https://doi.org/10.1016/j.jorganchem.2015.05.053