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RESEARCH PRODUCT

Anthracene Based Conjugated Polymers: Correlation between π−π-Stacking Ability, Photophysical Properties, Charge Carrier Mobility, and Photovoltaic Performance

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This article reports on the synthesis, characterization and properties of a series of anthracene−containing poly(p-phenylene-ethynylene)-alt-poly(p-phenylene-vinylene)s (PPE−PPV) copolymers with general constitutional unit (Ph−C≡C−Anthr−C≡C−Ph−CH═CH−Ph−CH═CH−)n denoted AnE-PV. Solely linear (AnE-PVaa, -ad, -ae) and solely branched (AnE-PVbb) as well as mixed linear and branched (AnE-PVab, -ac, -ba, -cc) alkoxy side chains were grafted to the backbone in order to tune the π−π-stacking ability of the materials. It has been possible to establish a correlation between π−π-stacking ability, absorptive behavior, charge carrier mobility, solar cell active layer nanoscale morphology and resulting photovoltaic performance. Solar cells energy conversion efficiencies between 0.34% and 3.14% were achieved. The best performance was achieved from AnE-PVab showing both stacking ability and highest π−π-stacking distance of 0.386 nm as compared to 0.380 nm for the others. Poorer performance resulted from polymers with no ...