Algebraic approach to vibrational spectra of tetrahedral molecules. First order infrared intensity model.

6533b86ffe1ef96bd12cddb8

RESEARCH PRODUCT

Algebraic approach to vibrational spectra of tetrahedral molecules. First order infrared intensity model.

Michel Loete Claude Leroy F. Collin

subject

Physics 010304 chemical physics [ PHYS.QPHY ] Physics [physics]/Quantum Physics [quant-ph]Infrared Operator (physics)Polyatomic ion Vibrational Spectra. Algebraic Approach. Intensity model Tetrahedral molecular geometry 010402 general chemistry 01 natural sciences Atomic and Molecular Physics and Optics 0104 chemical sciences Dipole [PHYS.QPHY]Physics [physics]/Quantum Physics [quant-ph]Quantum mechanics 0103 physical sciences Molecule Physical and Theoretical Chemistry Algebraic number Atomic physics Spectroscopy Group theory [PHYS.QPHY] Physics [physics]/Quantum Physics [quant-ph]

description

International audience; The algebraic approach we have proposed to describe the vibrational stretching modes of polyatomic molecules (Leroy and Michelot, J. Mol. Spectrosc. 151, 71–96 (1992); Can. J. Phys. 72, 274–289 (1994)) is applied to the silane molecule for up to seven quanta. We then suggest a form of the dipole operator adapted to the (n000) local states by combining the strength of group theory method with the necessity of a compact formulation.

year	journal	country	edition	language
1995-09-11

https://hal.science/hal-00461902

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