6533b86ffe1ef96bd12ce618

RESEARCH PRODUCT

Tungsten-mannitol and sorbitol complexes: Structural characterization by IR and carbon-13 nuclear magnetic resonance spectroscopy

Jose Antonio RamirezAntonio CervillaElisa Llopis

subject

chemistry.chemical_classificationAqueous solutionChemistryCarbon-13Infrared spectroscopychemistry.chemical_elementNuclear magnetic resonance spectroscopyTungstenInorganic ChemistryNuclear magnetic resonanceMaterials ChemistryPhysical chemistryMoleculePhysical and Theoretical ChemistryInorganic compoundStoichiometry

description

Abstract Polarimetric and spectrophotometric studies of the mannitol-tungsten(IV) system show the formation of three table complexes. Their stoichiometries, degrees of condensation and interconversion equilibria have been studied. The structure of these compounds has been investigated by 13C NMR spectroscopy in aqueous solution and by IR spectroscopy in the solid state for the two species stable at pH

https://doi.org/10.1016/s0277-5387(00)87140-5