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RESEARCH PRODUCT

Comment on “Molten salt synthesis of barium molybdate and tungstate microcrystals”

Daniel Errandonea

subject

Materials scienceBand gapMechanical EngineeringInorganic chemistrychemistry.chemical_elementBariumElectronic structureMolybdateCondensed Matter Physicschemistry.chemical_compoundMicrocrystallinechemistryTungstateMechanics of MaterialsScheeliteGeneral Materials ScienceMolten salt

description

Abstract In this comment we discuss recent results presented by P. Afanasiev on the optical properties of microcrystalline BaMoO 4 and BaWO 4 [Materials Letters 61 (2007) 4622]. Its aim is to show that the band-gap energy reported in that work for BaWO 4 is not reliable and largely underestimate the correct value. As a consequence of it, the challenge made in Ref. [P. Afanasiev, Materials Letters 61 (2007) 4622] to the previous understanding of the electronic structure of scheelite-type compounds is not valid.

https://doi.org/10.1016/j.matlet.2008.08.041