Search results for "Barium"
showing 10 items of 262 documents
CCDC 1859264: Experimental Crystal Structure Determination
2020
Related Article: Fernando Machado dos Santos, Meiry Edivirges Alvarenga, Ana Karoline Silva Mendanha Valdo, Renato Rabelo, Danielle Cangussu de Castro Gomes, Ângelo de Fátima, Thiago Vinicius Costa Lara, Cleiton Moreira da Silva, Thiago Teixeira Tasso, João Honorato Araujo Neto, Alzir Azevedo Batista, Alejandro Pedro Ayala, Javier Alcides Ellena, Vinicius Ferraz Guimarães, Cecília Maria Alves Oliveira, Lidya Cardozo da Silva, Boniek Gontijo Vaz, Felipe Terra Martins|2020|Chem.Commun.|56|15024|doi:10.1039/D0CC07043B
Bandgap behavior and singularity of the domain-induced light scattering through the pressure-induced ferroelectric transition in relaxor ferroelectri…
2018
[EN] In this letter, we have investigated the electronic structure of A(x)Ba(1-x)Nb(2)O(6) relaxor ferroelectrics on the basis of optical absorption spectroscopy in unpoled single crystals with A = Sr and Ca under high pressure. The direct character of the fundamental transition could be established by fitting Urbach's rule to the photon energy dependence of the absorption edge yielding bandgaps of 3.44(1) eV and 3.57(1) eV for A = Sr and Ca, respectively. The light scattering by ferroelectric domains in the pre-edge spectral range has been studied as a function of composition and pressure. After confirming with x-ray diffraction the occurrence of the previously observed ferroelectric to pa…
Polarization and acoustic properties of barium-modified lead-free potassium–sodium niobate ceramics
2017
The publication costs of this article were covered by the Estonian Academy of Sciences and the University of Tartu.
X-ray and dielectric characterization of Co doped tetragonal BaTiO3 ceramics
2016
ABSTRACTThe crystal structure modifications of BaTiO3 induced by cobalt doping were studied. The polycrystalline (1 − x)BaTiO3 + xCo2O3 samples, with x ≤ 10 wt.%, were prepared by high temperature sintering conventional method. According to X-ray phase and structural characterization, performed by full-profile Rietveld refinement technique, all synthesized samples showed tetragonal symmetry perovskite structure with minor amount of parasitic phases. Pure single-phase composition has been detected only in the low level of doping BaTiO3. It was indicated that substitution of Co for the Ti sites in the (1 − x)BaTiO3 + xCo2O3 series led to decrease of tetragonality (c/a) of the BaTiO3 perovskit…
Domain Walls Motions in Barium Titanate Ceramics
1996
The shear modulus and mechanical loss at low frequencies (0.01, 0.3, 1 Hz) are measured by an inverted pendulum for BaTiO 3 ceramic with large grain sizes. The permittivity and dielectric losses are also investigated for the same material at higher frequencies between 1 and 100 kHz as function of temperature. Those results show several relaxation peaks in the ferroelectric phases. The activation energy of each peak is obtained to be 0.29, 0.45, 0.68, 0.92 eV. The influences of strain amplitude and thermal treatments are studied specially for the mechanical relaxation peak located in the tetragonal phase. All the relaxation peaks could be associated to the interaction of oxygen vacancies in …
The effect of bias field on the dielectric response of Ba0.95Pb0.05TiO3+Со2О3
2021
The nature of the dielectric response in ferroelectric ceramics Ba0.95Pb0.05TiO3+Со2О3 (BPTC) under the influence of a constant bias field EB in the phase transition region is studied. It is found ...
The past distribution of Abies nebrodensis (Lojac.) Mattei: results of a multidisciplinary study
2019
The present study provides a critical review of the available historical data on the distribution of Abies nebrodensis, a fir tree endemic to Sicily. The only (somewhat ambiguous) references to its occurrence on Mount Etna date back to the 1st century bc and refer back to the 3rd century bc. Although the botanical and forestry literature and the very few surviving herbarium specimens do not prove that A. nebrodensis grew outside the Madonie mountain range, several indications suggest its past occurrence on other Sicilian mountain ranges such as the Erei, Nebrodi, and probably also Sicani mountains. The results of the most recent pollen investigations (still ongoing) point to the disappearan…
Assessment of the conservation status of the mat-forming lichens Cladonia subgenus Cladina in Italy
2015
Cladina species are likely to suffer the impact of human pressure, resulting in a potential, as well as currently unknown, extinction risk for some of them. In this study, we used herbarium specimen data and literature data combined with geographic information system (GIS)-based analyses to assess the threatened status of Italian Cladina species according to IUCN criteria. A total of 485 records, reported during the period 1833–2013, were evaluated. Biological traits, habitat requirements and distribution patterns were used to infer species extinction risk. Extent of occurrence and area of occupancy have been calculated at the national scale, based on a 2 km × 2 km cell grid. The potential …
Riella heliospora (Riellaceae) a new monoicous species of Riella subgenus Trabutiella from California
2012
14 páginas, 8 figuras, 1 tabla.
Phycological Herbaria as a Useful Tool to Monitor Long-Term Changes of Macroalgae Diversity: Some Case Studies from the Mediterranean Sea
2020
The Mediterranean Sea is currently experiencing a decline in the abundance of several key species, as a consequence of anthropogenic pressures (e.g., increase in human population, habitat modification and loss, pollution, coastal urbanization, overexploitation, introduction of non-indigenous species and climate change). Herbaria and natural history collections are certainly fundamental for taxonomic studies, but they are also an invaluable, if currently underestimated, resource for understanding ecological and evolutionary responses of species to environmental changes. Macroalgae herbarium collections, which are really consistent (ranging from 200,000 to approximately 500,000 specimens) in …