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RESEARCH PRODUCT
( n -Bu 4 N) 2 [Fe(dcbdt) 2 ] 2 . Synthesis, crystal structure and magnetic characterisation
João C. WaerenborghVasco GamaR.t. HenriquesHelena AlvesDulce SimãoCarlos Giménez-saizHorácio M. NovaisIsabel SantosManuel Almeidasubject
Inorganic ChemistryDiffractionCrystallographyMagnetizationChemistryMössbauer spectroscopyMaterials ChemistryAntiferromagnetismCrystal structurePhysical and Theoretical ChemistryTriclinic crystal systemSingle crystalMagnetic susceptibilitydescription
Abstract The ( n -Bu 4 N) 2 [Fe(dcbdt) 2 ] 2 complex, where 4,5-dicyanobenzene-1,2-dithiolate (dcbdt), was prepared and characterised by X-ray diffraction, Mossbauer spectroscopy and magnetisation measurements. The crystal structure as determined by single crystal X-ray diffraction is triclinic, space group P 1 with cell parameters a =9.5660(1) A, b =13.0200(2) A, c =16.0850(2) A, α =67.554°(1), β =86.797°(1), γ =70.523°(1), V =1738.77(4) A 3 and it consists in strongly dimerised [Fe(dcbdt) 2 ] − units, which are stacked side by side as chains along a . The magnetic susceptibility shows that the [Fe(dcbdt) 2 ] − units have a low spin S =1/2 configuration and, besides a strong intradimer antiferromagnetic interaction, present also a significant interdimer antiferromagnetic interaction mediated by short side contacts.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2003-07-01 | Polyhedron |