Palladium-Catalyzed Synthesis of Mono- and Diphosphorylated 1,10-Phenanthrolines

6533b870fe1ef96bd12cf2ff

RESEARCH PRODUCT

Palladium-Catalyzed Synthesis of Mono- and Diphosphorylated 1,10-Phenanthrolines

N. S. Gulyukina N. S. Gulyukina Irina Beletskaya Irina P. Beletskaya Roger Guilard Alla Bessmertnykh Lemeune Christine Stern Alexandre Mitrofanov Alexandre Mitrofanov

subject

chemistry.chemical_classification Base (chemistry)010405 organic chemistry Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences Medicinal chemistry Catalysis 3. Good health 0104 chemical sciences Catalysis chemistry.chemical_compound chemistry [CHIM]Chemical Sciences Triethylamine ComputingMilieux_MISCELLANEOUS Palladium

description

A general protocol for the coupling of mono- and dihalo-1,10-phenanthrolines with diethyl phosphite is reported. This reaction proceeds smoothly in the presence of a Pd(OAc)2/dppf catalytic system and triethylamine as a base.

year	journal	country	edition	language
2012-12-07	Synthesis

https://doi.org/10.1055/s-0032-1317517

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