6533b870fe1ef96bd12cfadf
RESEARCH PRODUCT
The ionic tin(IV) complex tri-μ2-methoxy-μ3-oxo-tris[di-tert-butyltin(IV)] tri-μ2-methoxy-bis[tert-butyldimethoxystannate(IV)]
Romain BurgatPhilippe RichardLaurent PlasseraudDanielle Ballivet-tkatchenkosubject
Tert butylTrisStannateStereochemistryIonic bondingchemistry.chemical_elementGeneral ChemistryCondensed Matter PhysicsMedicinal chemistryTrigonal bipyramidal molecular geometrychemistry.chemical_compoundchemistryOctahedronSN2 reactionGeneral Materials ScienceTindescription
The solid-state of the title compound, [Sn3(C4H9)6(CH3O)3O][Sn2(C4H9)2(CH3O)7], consists of distinct [tBu6Sn3(μ-OCH3)3(μ3-O)]+ cations and [tBu2Sn2(OCH3)4(μ-OCH3)3]− anions, apparently formed as a result of slow hydrolysis of pure di(tert-butyl)dimethoxystannane, tBu2Sn(OCH3)2. In the monocation, the coordination about the Sn atoms is distorted trigonal bipyramidal, and, in the monoanion, distorted octahedral. The trigonal bipyramidal arrangement induces planarity of the Sn3O4 motif.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2004-05-22 | Acta Crystallographica Section E Structure Reports Online |