6533b870fe1ef96bd12cfddb
RESEARCH PRODUCT
Crystal structure of a CsF-uranyl-salen complex. An unusual cesium-chlorine coordination.
Luigi MandoliniMaija NissinenKari RissanenMassimo CamettiAntonella Dalla Cortsubject
inorganic chemicalsChloroformCoordination sphereInorganic chemistrychemistry.chemical_elementCrystal structureUranylIonInorganic ChemistrySolventchemistry.chemical_compoundchemistryCaesiumPolymer chemistryChlorinePhysical and Theoretical Chemistrydescription
Complexation of CsF with the ditopic uranyl-salen receptor results in a solid-state structure, in which the coordination sphere of cesium is filled by ligation to one of the chlorine atoms of the solvent chloroform. This X-ray structure is the first example of chloroform ligation to an alkali-metal ion.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2006-01-01 | Inorganic chemistry |