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RESEARCH PRODUCT
The conductance of lithium-7 fluoride in dioxane-water mixtures at 25�C
Filippo AccascinaRaymond M. FuossAlessandro D'apranosubject
ChemistryIsotopes of lithiumInorganic chemistryBiophysicsAnalytical chemistryConductanceBiochemistryGibbs free energySolventchemistry.chemical_compoundsymbols.namesakeMolar volumePairingsymbolsPhysical and Theoretical ChemistrySolvent effectsMolecular BiologyFluoridedescription
Conductance data for lithium-7 fluoride in dioxane-water mixtures covering the range 78.35>D>36 in dielectric constant are presented. These data and other previous data on lithium-7 chloride and lithium-7 iodide were analyzed by the Fuoss 1980 conductance equation in order to find the limiting conductance Δo, the pairing distance R and the conductometric association constant Kλ. Setting Ka=Kλ/VM (where VM is the molar volume of the solvent), the thermodynamic pairing constant and the corresponding change of the free energy Δg were calculated. Correlation among the values found for R and Δg=Δh−TΔs and the properties characteristic of the ions and solvents are discussed.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1990-01-01 | Journal of Solution Chemistry |