Isoprene/Styrene Tapered Multiblock Copolymers with up to Ten Blocks: Synthesis, Phase Behavior, Order, and Mechanical Properties

6533b871fe1ef96bd12d0e90

RESEARCH PRODUCT

Isoprene/Styrene Tapered Multiblock Copolymers with up to Ten Blocks: Synthesis, Phase Behavior, Order, and Mechanical Properties

Christian Rüttiger George Floudas Markus Gallei Markus Mezger Tobias Johann Holger Frey Axel H. E. Müller Marvin Steube Michael Appold Eftyxis Galanos

subject

Materials science Polymers and Plastics Cyclohexane Organic Chemistry Multiblock copolymer Synthesis Phase 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Styrene Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Copolymer Order (group theory)Reactivity (chemistry)0210 nano-technology Isoprene

description

The living anionic copolymerization of isoprene and styrene in cyclohexane affords tapered block copolymers due to the highly disparate reactivity ratios of rI = 12.8 and rS = 0.051. Repeated addit...

year	journal	country	edition	language
2018-12-13	Macromolecules

https://doi.org/10.1021/acs.macromol.8b01961

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