6533b871fe1ef96bd12d0f96
RESEARCH PRODUCT
Proton-Induced Multiple Changes of the Absorption and Fluorescence Spectra of Amino-Aza-Oligo(Phenylenevinylene)s
Heiner DetertVolker SchmittStefan GlangJasmin Preissubject
ProtonChemistrySolvatochromismProtonationChromophorePhotochemistryFluorescence spectraFluorescenceAtomic and Molecular Physics and OpticsAldol condensationsense organsEmission spectrumElectrical and Electronic EngineeringAbsorption (chemistry)description
Fluorescent dyes with a high sensitivity of their optical spectra towards changes of the environment were prepared via aldol condensation or Horner olefinations. The main chromophore is a quadrupolar N-substituted 1,4-distyrylbenzene which allows protonation and complexation at various positions resulting in a series of different and significant changes of the optical spectra. The sensitivity of the absorption and emission spectra on solvent polarity, acid, and cations is reported.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2008-09-02 | Advances in Science and Technology |