A new monomeric interpretation of intrinsic optical bistability observed in Yb3+-doped bromide materials

6533b871fe1ef96bd12d0fc3

RESEARCH PRODUCT

A new monomeric interpretation of intrinsic optical bistability observed in Yb3+-doped bromide materials

S.r. Luthi Anna Napoli F. Ciccarello Antonino Messina

subject

Chemical Physics (physics.chem-ph)Quantum Physics Bistability optical bistability rare earth ions Stereochemistry Doping FOS: Physical sciences Physics::Optics General Physics and Astronomy Nonlinear optics Optical bistability Ion Coupling (electronics)chemistry.chemical_compound optical bistability chemistry Bromide Chemical physics Physics - Chemical Physics Molecular vibration rare earth ions Physical and Theoretical Chemistry Quantum Physics (quant-ph)

description

We present a mechanism able to show intrinsic bistable behaviour involving single Yb3+ ions embedded into bromide lattices, in which intrinsic optical bistability (IOB) has been observed. The mechanism is based on the experimentally found coupling between the Yb3+ ion and the totally symmetric local mode of vibration of the [YbBr6]3- coordination unit. The model reproduces the IOB observed in CsCdBr3:1% Yb3+ and allows to understand the experimentally found presence of the phenomenon in the other bromides, but its absence in Cs3Lu2Cl9:Yb3+.

year	journal	country	edition	language
2003-09-18	Chemical Physics Letters

https://doi.org/10.1016/j.cplett.2003.09.026

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