Unambiguous structure elucidation of heterocyclic products from condensation-cyclisation reactions of enaminones by 2D INADEQUATE and 15 N NMR

6533b871fe1ef96bd12d1912

RESEARCH PRODUCT

Unambiguous structure elucidation of heterocyclic products from condensation-cyclisation reactions of enaminones by 2D INADEQUATE and 15 N NMR

Johannes C. Liermann Mohamed Hilmy Elnagdi Herbert Meier

subject

Computational chemistry Chemistry Stereochemistry Condensation General Materials Science General Chemistry Tautomer

description

The reaction of enaminones with 3-amino-2-cyanopent-2-enedinitrile can lead to an array of 12 possible products, depending on the reaction pathway and tautomerization. The use of 2D INADEQUATE and 15N NMR for the unambiguous structure elucidation of the reaction products is discussed in this manuscript. Copyright © 2012 John Wiley & Sons, Ltd.

year	journal	country	edition	language
2012-11-07	Magnetic Resonance in Chemistry

https://doi.org/10.1002/mrc.3897

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