Phosphororganische Verbindungen, XIV. Addukte aus tertiären Phosphinen und Carboniumsalzen

6533b871fe1ef96bd12d192f

RESEARCH PRODUCT

Phosphororganische Verbindungen, XIV. Addukte aus tertiären Phosphinen und Carboniumsalzen

subject

Inorganic Chemistry Chemistry Medicinal chemistry

description

Eine Reihe resonanzstabilisierter Carboniumsalze addiert sich an tertiare Phosphine unter Bildung von quartaren Phosphoniumsalzen. Triathoxycarboniumtetrafluoroborat wirkt dagegen (unter Ruckbildung von Diathylcarbonat) als Alkylierungsmittel. Das aus Campher bereitete Phosphoniumsalz XI spaltet das tertiare Phosphin als Salz unter Bildung von Athyl-campher-enolather ab.

year	journal	country	edition	language
1958-01-01	Chemische Berichte

https://doi.org/10.1002/cber.19580910115

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